CAT_VALIDATION_ERROR_ADDITIONAL_IMAGES_TAG_INVALID fires when image tags supplied with extra media use unsupported characters or values. Tags must be short alphanumeric labels matching Snap's accepted tag list.
Snap Catalog Manager requires product images that are publicly reachable, sized within the platform's bounds, in supported formats (JPEG/PNG typically), and free of overlays, watermarks, retailer logos, or text callouts. This issue trips when one of those constraints is broken.