Google found a value in your gtin field, but it doesn't pass Google's validation — either the format is wrong or the check digit fails.
The most common cause is a check-digit mismatch. GTINs include a final calculated digit that validates the rest of the number. If even one digit is off, the whole code is rejected. Other common causes: leading zeros stripped by Excel, GTINs from restricted ranges (e.g., starting with 04 or 05), or pasting an MPN where a GTIN belonged.